Metallo-intercalators and metallo-insertors
نویسندگان
چکیده
منابع مشابه
Metallo-intercalators and metallo-insertors.
Since the elucidation of the structure of double helical DNA, the construction of small molecules that recognize and react at specific DNA sites has been an area of considerable interest. In particular, the study of transition metal complexes that bind DNA with specificity has been a burgeoning field. This growth has been due in large part to the useful properties of metal complexes, which poss...
متن کاملMME ( membrane metallo - endopeptidase )
Location: 3q25.2 Note: Membrane metallo-endopeptidase (MME) is a 100-kD type II transmembrane glycoprotein originally described on human acute lymphoblastic leukemia cell lines and therefore it was originally designated as common acute lymphocytic leukemia antigen (CALLA). MME is a neutral endopeptidase that cleaves peptides at the amino side of hydrophobic residues and inactivates several pept...
متن کاملMetallo-supramolecular cyclic polymers.
Cyclic brush polymers represent an exciting new macromolecular topology. For the first time, this new topology has been combined with metallo-supramolecular interactions to construct novel cyclic brush polymers. Here, ring-expansion metathesis polymerization was used to synthesize a universal cyclic template with a polynorbornene backbone, which was further modified with the metal-chelating syn...
متن کاملCompetition between drum and quasi-planar structures in RhB18-: motifs for metallo-boronanotubes and metallo-borophenes.
Metal-doped boron clusters provide new opportunities to design nanoclusters with interesting structures and bonding. A cobalt-doped boron cluster, CoB18-, has been observed recently to be planar and can be viewed as a motif for metallo-borophenes, whereas the D9d drum isomer as a motif for metallo-boronanotubes is found to be much higher in energy. Hence, whether larger doped boron drums are po...
متن کاملMetalloproteins, Metallo-enzymes and Heterogeneous Catalys
An inspection of the active site region of metallo-enzymes leads to two conclusions. (i) Individual attacking groups usually have uncommon physical properties. (ii) The active site region is cooperatively linked with a large part of the enzyme. Such an interaction is common to heterogeneous catalysts but is absent in homogeneous catalysts. It is concluded that the energetics of catalysis requir...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Communications
سال: 2007
ISSN: 1359-7345,1364-548X
DOI: 10.1039/b710949k